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Dual Palladium/Photoredox-Catalyzed Enantioselective and Regioselective Decarboxylative Hydroaminoalkylation of Allenes by Zheng, Jun (author);Nikbakht, Ali (author);Breit, Bernhard (author) is a Chemistry article available to read on EtoBox.
What is Dual Palladium/Photoredox-Catalyzed Enantioselective and Regioselective Decarboxylative Hydroaminoalkylation of Allenes about?
A dual palladium/photoredox-catalyzed regio-and enantioselective decarboxylative hydroaminoalkylation of allenes with amino acids is reported. This mild, redox-neutral, and atom-economic process allows access to a range of protected vinyl 1,2amino ethers in good yields with high levels of branched and enantioselectivity, when alkoxyallenes were employed. Conversely, with alkyl-and aryl-substituted terminal allenes as the substrates, a linear-selective decarboxylative hydroaminoalkylation of allenes is realized in high regio-and E/Z selectivities with a Pd/rac-BINAP catalytic system.
Who reads Dual Palladium/Photoredox-Catalyzed Enantioselective and Regioselective Decarboxylative Hydroaminoalkylation of Allenes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Zheng, Jun (author);Nikbakht, Ali (author);Breit, Bernhard (author)
- Publisher
- American Chemical Society (ACS)
- Published
- 2021
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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