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Chemical identification and quantification of volatile organic compounds emitted by sewage sludge 1 1. Introduction 2 2. Materials and methods 2 2.1. Sample description 2 2.2. Chamber experiments 3 2.3. PTR-Qi-ToF-MS measurements 3 2.4. Double bond equivalent method 3 2.5. Statistical analysis 3 3. Results 4 3.1. Distribution of VOCs in the samples 4 3.2. Classification of HC by the DBE method 4 3.3. Emission characteristics of VOCs 4 3.4. Comparison between the samples 6 4. Discussion 6 4.1. Hydrocarbons 6 4.1.1. Aliphatic and alicyclic compounds 7 4.1.2. Terpenes 7 4.1.3. Aromatic compounds 9 4.2. Volatile organic sulphur compounds (VOSCs) 9 4.3. Oxygenated volatile organic compounds (OVOCs) 9 4.4. Nitrogenated organic compounds 10 4.5. Other gas phase emissions 10 4.6. Impact of treatment stage on VOC emissions 10 5. Conclusions and environmental implications 11 CRediT authorship contribution statement 11 Declaration of competing interest 11 Acknowledgements 11 Appendix A. Supplementary data 11 References 11

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Language

UND

Category

nonfiction