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An Allosteric Metal–Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation by Beibei Zhou; Tengwu Zeng; Zhao‐Lin Shi; Gen Zhang; Satoshi Horike; Yue‐Biao Zhang is a Chemistry article available to read on EtoBox.
What is An Allosteric Metal–Organic Framework That Exhibits Multiple Pore Configurations for the Optimization of Hydrocarbon Separation about?
## Abstract The function of allosteric enzymes can be activated or inhibited through binding of specific effector molecules. Herein, we describe how the skeletal deformation, pore configuration, and ultimately adsorptive behavior of a dynamic metal–organic framework (MOF), (Me~2~NH~2~)[In(atp)]~2~ (in which atp=2‐aminoterephthalate), are controlled by the allocation and orientation of its counter ions triggered by the inclusion/removal of different guest molecules. The power of such allosteric control in MOFs is highlighted through the optimization of the hydrocarbon separation performance by achieving multiple pore configurations but without altering the chemical composition.
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- Author
- Beibei Zhou; Tengwu Zeng; Zhao‐Lin Shi; Gen Zhang; Satoshi Horike; Yue‐Biao Zhang
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley - V C H Verlag GmbbH & Co.; Wiley (ISSN 1861-4728)
- Published
- 2019
- Language
- EN
- Field
- Chemistry (Physical Sciences)