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The document describes research into iodine-catalyzed aminosulfonation of hydrocarbons using imidoiodinanes. The researchers were able to aminofunctionalize a range of benzylic and some aliphatic hydrocarbons under mild conditions. Mechanistic studies provided evidence for a stepwise reaction pathway in C-N bond formation. Investigation led to the isolation of a novel aminating agent formulated as (ArSO2N)xIy, which may be the active species in the reaction. Optimization studies identified iodine as an effe

Author

Diogomussum

Language

EN