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Gas‐phase elimination reactions of 4‐arylideneimino‐2‐cyanoethyl‐1,2,4‐triazol‐3(2 H )‐ones, their thione analogues and 2‐glucosyl‐1,2,4‐triazole‐3(2 H )‐thiones: a kinetic and mechanistic study by Nouria A. Al‐Awadi; Yehia A. Ibrahim; Hicham Dib; Kamini Kaul is a Chemistry article available to read on EtoBox.

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## Abstract Several 4‐arylidenimino‐2‐cyanoethyl‐1,2,4‐triazol‐3(2__H__)‐ones, their 3(2__H__)‐thiones and 2‐glucosyl‐1,2,4‐triazol‐3(2__H__)‐thiones (**1–12**) were synthesized. Selective pyrolytic deprotection of these derivatives was studied in the gas phase and the kinetics of the reactions were measured for each compound. First‐order rate constants measured over a 45 °C temperature range were used to calculate the Arrhenius activation parameters. A comparison of the products and the kinetic behavior of the thermal decomposition of these compounds are discussed. Copyright­© 2002 John Wiley & Sons, Ltd.

Who reads Gas‐phase elimination reactions of 4‐arylideneimino‐2‐cyanoethyl‐1,2,4‐triazol‐3(2 H )‐ones, their thione analogues and 2‐glucosyl‐1,2,4‐triazole‐3(2 H )‐thiones: a kinetic and mechanistic study?

Author

Nouria A. Al‐Awadi; Yehia A. Ibrahim; Hicham Dib; Kamini Kaul

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0894-3230)

Published

2002

Language

EN

Field

Chemistry (Physical Sciences)