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Can I read Metalation of dibenzenechromium by N,N,N′N′-tetramethylethylenediamine complexes of n-butyllithium and phenyllithium on EtoBox?
Metalation of dibenzenechromium by N,N,N′N′-tetramethylethylenediamine complexes of n-butyllithium and phenyllithium by C. Elschenbroich is a Chemistry article available to read on EtoBox.
What is Metalation of dibenzenechromium by N,N,N′N′-tetramethylethylenediamine complexes of n-butyllithium and phenyllithium about?
Dibenzenechromium is metalated by n-butyllithium in presence of TMEDA. The extent and orientation of metalation were investigated by mass spectrometric analysis of the products after quenching with D,O.A lithium substituent on dibenzenechromium strongly activates the molecuIe for further melalation. Competition metalation of dibenzenechromium/benzene mixtures demonstrated the enhanced rate of metalation and therefore increased kinetic C-H acidity of the benzene molecule bound to chromium in a x-complex.
Who reads Metalation of dibenzenechromium by N,N,N′N′-tetramethylethylenediamine complexes of n-butyllithium and phenyllithium?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- C. Elschenbroich
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 1968
- Language
- EN
- Field
- Chemistry (Physical Sciences)