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Luminescence mechanism of Sm doped MgAl2O4 nanophosphors: Role of nanoparticle size, samarium content and structural defects 1 1 Introduction 1 2 Synthesis and characterization of samples 2 3 Luminescence spectra studies 3 3.1 Experimental luminescence spectra 3 3.2 Surface segregation 5 4 MCFT calculations: parameters of the problem 6 4.1 Calculations of free Sm3+ spectrum 6 4.2 MCFT calculation of effective charges of ligands that create a crystal field around Sm3+ ions in MgAl2O4 7 5 Modelling of possible Sm–O coordination complexes and its verification by electron paramagnetic resonance 7 6 The luminescence spectra simulation of Sm doped MgAl2O4 spinels 9 7 Conclusions 12 Contributor roles taxonomy 13 Declaration of competing interest 13 Acknowledgments 13 References 13
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- Language
- EN
- Category
- nonfiction
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