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Can I read 1,1,1-Trichloro-3-bromo-3-phenylpropane as a photoinitiator in the polymerization of styrene on EtoBox?
1,1,1-Trichloro-3-bromo-3-phenylpropane as a photoinitiator in the polymerization of styrene by C.A. Barson; R.A. Batten; J.C. Robb is a Materials Science article available to read on EtoBox.
What is 1,1,1-Trichloro-3-bromo-3-phenylpropane as a photoinitiator in the polymerization of styrene about?
The photoinitiated reaction between styrene and l,l.l-trichloro-3-bromo-3-phenylpropane at 30 :' has been studied. The latter compound undergoes transfer with polystyryl radicals less readily than styrene dibromide and much less readily than bromotrichloromethane. The kinetic behaviour is consistent with a scheme involving primary radical termination, which would be enhanced bx the regeneration of primary radicals in the transfer step. An alternative explanation invokes the participation of monomer in a rate-controlling initiation reaction with primary radicals which have escaped from their solvent cages. Rate constants for the individual steps are quoted.
Who reads 1,1,1-Trichloro-3-bromo-3-phenylpropane as a photoinitiator in the polymerization of styrene?
It is typically read by researchers, students, and practitioners in Materials Science.
- Author
- C.A. Barson; R.A. Batten; J.C. Robb
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0014-3057)
- Published
- 1975
- Language
- EN
- Field
- Materials Science (Physical Sciences)