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Potential‐free Sodium‐induced Degradation of Silicon Heterojunction Solar Cells by Xiaodong Li; Yuhao Yang; Kai Jiang; Shenglei Huang; Wenjie Zhao; Zhenfei Li; Guangyuan Wang; Anjun Han; Jian Yu; Dongdong Li; Fanying Meng; Liping Zhang; Zhengxin Liu; Wenzhu Liu is a Engineering article available to read on EtoBox.

What is Potential‐free Sodium‐induced Degradation of Silicon Heterojunction Solar Cells about?

Silicon-based photovoltaic (PV) modules suffer from potential-induced degradation (PID) caused by sodium (Na) permeation, which is present in large quantities in sodalime glass. Here, we report that Na atoms can decrease the performance of amorphous/crystalline silicon heterojunction (SHJ) solar cells without the help of a voltage bias. The three degradation stages are investigated in this work. First, H 2 O molecules open channels for Na transport in the transparent conductive oxide (TCO), while the device performance remains almost unchanged. Next, when Na atoms reach the boron-doped hydrogenated amorphous silicon (p-a-Si:H), the field passivation is poisoned, leading to a great decline in the fill factor (FF), whereas the open-circuit voltage (V oc ) only slightly declines. Finally, Na atoms further diffuse into the intrinsic a-Si:H layer and c-Si surface, resulting in a substantial decrease in V oc . These findings have important implications for the installation of SHJ solar modules in Na-abundant environments. As a feasible solution, we demonstrate that a compact SiO 2 thin film can efficiently prevent H 2 O molecules from penetrating into the TCO layer and therefore guarante

Who reads Potential‐free Sodium‐induced Degradation of Silicon Heterojunction Solar Cells?

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Author
Xiaodong Li; Yuhao Yang; Kai Jiang; Shenglei Huang; Wenjie Zhao; Zhenfei Li; Guangyuan Wang; Anjun Han; Jian Yu; Dongdong Li; Fanying Meng; Liping Zhang; Zhengxin Liu; Wenzhu Liu
Publisher
Wiley
Published
2023
Language
EN
Field
Engineering (Physical Sciences)

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