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Self-assembly syntheses and crystal structures of triphenyltin(IV) phenylphosphate: A 1D polymer and a dimer of 24-membered macrocycle by Chunlin Ma; Mingqing Yang; Rufen Zhang; Jikun Li is a Materials Science article available to read on EtoBox.

What is Self-assembly syntheses and crystal structures of triphenyltin(IV) phenylphosphate: A 1D polymer and a dimer of 24-membered macrocycle about?

Two novel organotin(IV) complexes of the types [(Ph 3 Sn) 4 (O 3 POPh) 2 ] n 1 and [(Ph 3 Sn) 6 (O 3 POPh) 3 ] 2 2 have been prepared by treatment of phenylphosphoric acid and the Ph 3 SnCl under different conditions. The complexes 1 and 2 were characterized by elemental analysis, IR and NMR ( 1 H, 13 C, 119 Sn) spectroscopy and X-ray crystallography diffraction analysis. The structure analyses reveal that complex 1 is an infinite 1D polymer and complex 2 is a dimer which contains two 24-membered macrocycles.

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Author

Chunlin Ma; Mingqing Yang; Rufen Zhang; Jikun Li

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 1387-7003)

Published

2007

Language

EN

Field

Materials Science (Physical Sciences)