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Symmetry reduction of benzene on Rh(111) by coadsorbed Na by G. Rosina; G. Rangelov; E. Bertel; H. Saalfeld; F.P. Netzer is a Physics and Astronomy article available to read on EtoBox.

Angle-resolved photoemission experiments using synchrotron radiation reveal a reduction from C& to C3v,av in the local symmetry of benzene on Rh( 11 I ) in the presence of coadsorbed Na. This is interpreted via a model of the coadsorbate layer in which the benzene molecules, adsorbed on-top in a pure benzene layer, occupy threefold hollow positions with a possible out-of-plane C-H bending distortion. The benzene energetics are influenced only weakly by coadsorbed Na.

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Author
G. Rosina; G. Rangelov; E. Bertel; H. Saalfeld; F.P. Netzer
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0009-2614)
Published
1987
Language
EN
Field
Physics and Astronomy (Physical Sciences)