Can I read Thermodynamic modelling of LiF–LnF3 and LiF–AnF3 phase diagrams on EtoBox?

Thermodynamic modelling of LiF–LnF3 and LiF–AnF3 phase diagrams by J.P.M. van der Meer; R.J.M. Konings; M.H.G. Jacobs; H.A.J. Oonk is a Materials Science article available to read on EtoBox.

What is Thermodynamic modelling of LiF–LnF3 and LiF–AnF3 phase diagrams about?

The phase diagrams of the LiF-LnF 3 series, where Ln = La-Sm, and of LiF-AnF 3 , where An = U, Pu, have been optimized using Redlich-Kister functions. The phase diagrams of LiF-AmF 3 and LiF-PuF 3 -AmF 3 have been calculated. The necessary Gibbs energy functions for americium trifluoride were defined by use of a semi-empirical method. The excess Gibbs energy terms, which are expressed as Redlich-Kister polynomials and describe the effect of interaction between the two fluoride components in the liquid phase, were obtained by translating the trends observed in the lanthanide trifluoride series into the actinide series. A single eutectic has been found in the LiF-AmF 3 system with the eutectic point at '33 mole% AmF 3 and at '951 K.

Who reads Thermodynamic modelling of LiF–LnF3 and LiF–AnF3 phase diagrams?

Author

J.P.M. van der Meer; R.J.M. Konings; M.H.G. Jacobs; H.A.J. Oonk

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-3115)

Published

2004

Language

EN

Field

Materials Science (Physical Sciences)