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Can I read The Reaction of α-Phenethyl Radicals with 1,4-Benzoquinone and 2,6-Di-tert-butyl-1,4-benzoquinone on EtoBox?
The Reaction of α-Phenethyl Radicals with 1,4-Benzoquinone and 2,6-Di-tert-butyl-1,4-benzoquinone by Paul S. Engel; Hee Jung Park; Hua Mo; Shaoming Duan is a Chemistry article available to read on EtoBox.
What is The Reaction of α-Phenethyl Radicals with 1,4-Benzoquinone and 2,6-Di-tert-butyl-1,4-benzoquinone about?
The absolute rate constant for 1,4-benzoquinone (BQ) irreversibly trapping a-phenethyl radicals (3) has been determined as 4.410 6 M À1 s À1 at 43 C using acyclic cis azoalkane 9c as a radical precursor. These reactants afford the hydroquinone mono ether 4 at 30 C but a mixture of products at elevated temperature. 2,6-Di-tert-butyl-1,4-benzoquinone (DTBQ) also reacts with 3 but the cyclohexadienone products are thermally labile.
Who reads The Reaction of α-Phenethyl Radicals with 1,4-Benzoquinone and 2,6-Di-tert-butyl-1,4-benzoquinone?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Paul S. Engel; Hee Jung Park; Hua Mo; Shaoming Duan
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 2010
- Language
- EN
- Field
- Chemistry (Physical Sciences)
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