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An Enantioselective Total Synthesis and Stereochemical Revision of (+)-Citrinadin B by Ke Kong; John A. Enquist; Monica E. McCallum; Genessa M. Smith; Takanori Matsumaru; Elnaz Menhaji-Klotz; John L. Wood is a Chemistry article available to read on EtoBox.
What is An Enantioselective Total Synthesis and Stereochemical Revision of (+)-Citrinadin B about?
This manuscript describes an enantioselective synthesis of the naturally occurring alkaloid citrinadin B. The synthetic effort revealed an anomaly in the original structural assignment that has led to the proposal of a stereochemical revision. This revision is consistent with the structures previously reported for a closely related family of alkaloids, PF1270A-C. The synthesis is convergent and employs a stereoselective intermolecular nitrone cyloaddition reaction as a key step.C itrinadin B (1) is the structurally least complex member in a family of related alkaloids that includes citrinadin A (2) and PF1270A-C (3-5, respectively, Figure ). Isolated from
Who reads An Enantioselective Total Synthesis and Stereochemical Revision of (+)-Citrinadin B?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Ke Kong; John A. Enquist; Monica E. McCallum; Genessa M. Smith; Takanori Matsumaru; Elnaz Menhaji-Klotz; John L. Wood
- Publisher
- American Chemical Society (ACS)
- Published
- 2013
- Language
- EN
- Field
- Chemistry (Physical Sciences)