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Facile C–N cleavage reactions of secondary and tertiary alkyl amines by P,O chelating rhodium and iridium complexes by Yasuhiro Yamamoto; Jouji Seta; Hiroshi Murooka; Xiao-Hong Han is a Materials Science article available to read on EtoBox.

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The reactions of Cp\*MCl(MDMPP-P,O) (1: M 1⁄4 Rh; 3: M 1⁄4 Ir; MDMPP-P ; O 1⁄4 P Ph 2 (C 6 H 3 -2-O-6-MeO)) with secondary or tertiary alkyl amine (R 2 NH or R 3 N) in the presence of KPF 6 underwent a C-N cleavage of amine to afford primary amine complex [Cp

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Author

Yasuhiro Yamamoto; Jouji Seta; Hiroshi Murooka; Xiao-Hong Han

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 1387-7003)

Published

2003

Language

EN

Field

Materials Science (Physical Sciences)