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A new simple synthesis of 1,3‐dideuterated malondialdehyde (3‐hydroxy[1,3‐^2^H~2~]‐2‐propenal) by Pietro Allevi; Mario Anastasia; Pierangela Ciuffreda is a Chemistry article available to read on EtoBox.

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## Abstract A synthetic route for obtaining 1‐butoxy‐1,3,3‐triethoxy[1,3‐^2^H~2~]propane a stable diacetal of the malondialdehyde, is described. The synthesis involves the condensation of deuterated butylvinyl ether with deuterated triethyl orthoformate in the presence of montmorillonite clay K‐10. The deuteration of butyl vinyl ether was accomplished via the intermediary formation of a stannane derivative which was quantitatively metallated by __n__‐butyllithium and then treated with ^2^H~2~O. From the diacetal the 1,3‐dideuterated malondialdehyde was obtained by a short treatment with acid ion exchange resin.

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Author

Pietro Allevi; Mario Anastasia; Pierangela Ciuffreda

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 0022-2135)

Published

1994

Language

EN

ISBN

9782580340615

Field

Chemistry (Life Sciences)