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Can I read Photochemical chloride anation and aquation of hexammine chromium(III) in acid solution on EtoBox?

Photochemical chloride anation and aquation of hexammine chromium(III) in acid solution by H.H. Krause; F. Wasgestian is a Chemistry article available to read on EtoBox.

What is Photochemical chloride anation and aquation of hexammine chromium(III) in acid solution about?

Photolysis of aqueous solutions of [Ck(NH3)a]3' (pH = 2.0) containing chloride ions produces [Cr-(NH,),H,O] 3+ and [Cr(NH3)gC7] '+. The competition between photoanation and photoaquation was studied as a function of CF concentration (eS M LiCl). The quantum yield for ammonia release remained constant over the whole concentration range (4 = 0.41). Comparable efficiency of anation and aquation was found between 2-3 M CT. A mechanism assuming a trigonal prismatic transition state is proposed for photosubstitution reactions of cr(lll) complexes.

Who reads Photochemical chloride anation and aquation of hexammine chromium(III) in acid solution?

It is typically read by researchers, students, and practitioners in Chemistry.

Author
H.H. Krause; F. Wasgestian
Publisher
Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)
Published
1978
Language
EN
Field
Chemistry (Physical Sciences)

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