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Can I read A standard for silver CP/MAS experiments on EtoBox?
A standard for silver CP/MAS experiments by Glenn H. Penner; Wenli Li is a Chemistry article available to read on EtoBox.
What is A standard for silver CP/MAS experiments about?
Silver methanesulfonate, AgSO3CH3, is a photo-stable, commercially available compound which is a superior 109Ag standard for setting up CP/MAS experiments. The 109Ag CP/MAS spectrum at moderate sample spinning speeds easily yields a single, relatively narrow peak with a single transient. The 109Ag chemical shift of solid AgSO3CH3 is 87.2 ppm with respect to a 9 M aqueous solution of AgNO3. The static spectrum yields chemical shift tensor components delta11=191 ppm, delta22=63 ppm and delta33=8 ppm. Therefore the span, Omega, is 183 ppm and the skew, kappa, is -0.39. These values are in accord with the known crystal structure.
Who reads A standard for silver CP/MAS experiments?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Glenn H. Penner; Wenli Li
- Publisher
- Elsevier Science; Elsevier ; Elsevier Inc.; Elsevier BV (ISSN 0926-2040)
- Published
- 2003
- Language
- EN
- Field
- Chemistry (Physical Sciences)