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Can I read Chemoselective Dehydrogenative Esterification of Aldehydes and Alcohols with a Dimeric Rhodium(ii) Catalyst on EtoBox?
Chemoselective Dehydrogenative Esterification of Aldehydes and Alcohols with a Dimeric Rhodium(ii) Catalyst by Junjie Cheng; Meijuan Zhu; Chao Wang; Junjun Li; Xue Jiang; Yawen Wei; Weijun Tang; Dong Xue; Jianliang Xiao is a Chemistry article available to read on EtoBox.
What is Chemoselective Dehydrogenative Esterification of Aldehydes and Alcohols with a Dimeric Rhodium(ii) Catalyst about?
Dehydrogenative cross-coupling of aldehydes with alcohols as well as dehydrogentive cross-coupling of primary alcohols to produce esters have been developed using a Rh-terpyridine catalyst. The catalyst demonstrates broad substrate scope and good functional group tolerance, affording esters highly selectively. The high chemoselectivity of the catalyst stems from its preference for dehydrogenation of benzylic alcohols over aliphatic ones. Preliminary mechanistic studies suggest that the active catalyst is a dimeric Rh(ii) species, operating a mechanism involving metal-base-metal cooperativity.
Who reads Chemoselective Dehydrogenative Esterification of Aldehydes and Alcohols with a Dimeric Rhodium(ii) Catalyst?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- Junjie Cheng; Meijuan Zhu; Chao Wang; Junjun Li; Xue Jiang; Yawen Wei; Weijun Tang; Dong Xue; Jianliang Xiao
- Published
- 2016
- Language
- EN
- Field
- Chemistry (Physical Sciences)