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A series of octahedral Cr(III) complexes with both redox innocent and non-innocent ligands was synthesized. The radical complexes were found to be intensely coloured and air sensitive. The complex Cr(DPM) 2 (bpy) was found to rapidly and quantitatively react with trityl bromide via an outer-sphere single electron transfer mechanism.

Author

Luis Francisco Lizcano Guzman

Language

EN