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What is Partition Function in Diatomic Molecules about?
This document discusses the calculation of internal energy and entropy for the translational, rotational, and vibrational modes of diatomic molecules using partition functions. It shows that: 1) The rotational energy (Er) of diatomic molecules is equal to RT and the rotational entropy (Sr) can be calculated as R[1 + ln(8π2IKT/σh2)]. 2) The vibrational energy (Ev) is equal to RThν0/(ehν0/kT - 1) and the vibrational entropy (Sv) is R[hν0/kT/(e hν0/kT -1) + ln(1 - e-hν
- Author
- NITISH KUMAR
- Language
- EN