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What is Probing Bowl To Bowl Inversion in Enantiopure Subphthalocyanines Cofacial Sn2 Vs Sn1 Pathways at A Tetracoordinate about?

The study investigates bowl-to-bowl (BtB) inversion in enantiopure boron subphthalocyanines (SubPcs) through ligand exchange reactions, revealing a dual mechanistic pathway involving both stereoretentive bimolecular (cSN2) and minor SN1-like processes. The findings indicate that the reaction kinetics and stereochemical outcomes are influenced by the electronic and steric properties of the macrocycle, the leaving group, and the Lewis acid strength. This research enhances the understanding of boron-centered s

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larahdiasl02

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