Can I read A New and Effective Method for Providing Optically Active Monosubstituted Malononitriles: Selective Reduction of α,β-Unsaturated Dinitriles Catalyzed by Copper Hydride Complexes on EtoBox?

A New and Effective Method for Providing Optically Active Monosubstituted Malononitriles: Selective Reduction of α,β-Unsaturated Dinitriles Catalyzed by Copper Hydride Complexes by Yunlai Ren; Xianlun Xu; Kunpeng Sun; Jian Xu is a Chemistry article available to read on EtoBox.

What is A New and Effective Method for Providing Optically Active Monosubstituted Malononitriles: Selective Reduction of α,β-Unsaturated Dinitriles Catalyzed by Copper Hydride Complexes about?

A copper hydride complex, which was generated in situ from CuOt-Bu, BINAP, and PhSiH 3 , was found to be a highly effective catalyst for the reduction of the C@C of a,b-unsaturated dinitriles. In addition to CuOt-Bu, some air and moisture stable Cu salts were also effective as catalyst precursors in this reduction. Herein, we have developed an effective method for providing optically active monosubstituted malononitriles.

Who reads A New and Effective Method for Providing Optically Active Monosubstituted Malononitriles: Selective Reduction of α,β-Unsaturated Dinitriles Catalyzed by Copper Hydride Complexes?

Author

Yunlai Ren; Xianlun Xu; Kunpeng Sun; Jian Xu

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0957-4166)

Published

2005

Language

EN

Field

Chemistry (Physical Sciences)