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Can I read Polyfluorobicyclo(2.2.1)heptanes—I on EtoBox?
Polyfluorobicyclo(2.2.1)heptanes—I by S.F. Campbell; R. Stephens; J.C. Tatlow is a Chemistry article available to read on EtoBox.
What is Polyfluorobicyclo(2.2.1)heptanes—I about?
The vapour-phase fluorination of bicyclo(2.2.l)heptadiene with cobaltic fluoride gave a complex mixture containing substantial amounts of perfluoro-, lH-undecafluoro-and lH,4Hdmfluorobicyclo(2.2.l)heptane. The formation of perf'luorocarbanions from the latter two compounds has been demonstrated by isotopic exchange in aqueous potassium hydroxide. The undecalluorobicyclo(2.2.l)heptyt anion has been formed also using methyl-lithium in ether at -55", and trapped by reaction with acetaldehyde, bromine, methyl bromide and deuterium oxide. Near room temperature lithium undecaftuorobicyclo(2.2.l)heptyl decomposed in a novel elimination process, thought to involve a transient bridgehead olefin, to give lithium fluoride and either 1-iodo-, or l-bromo-, nonafluorobicyclo(2.2.l)hept-2ene, depending on whether the methyl-lithium used to generate the anion was prepared from methyl iodide or methyl bromide, respectively. A similar decomposition in the presence of furan produced a furan adduct.
Who reads Polyfluorobicyclo(2.2.1)heptanes—I?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- S.F. Campbell; R. Stephens; J.C. Tatlow
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4020)
- Published
- 1965
- Language
- EN
- Field
- Chemistry (Physical Sciences)