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This study investigates the development of (Cu, Zr)/a-C thin coatings on TC4 alloy to enhance mechanical properties and corrosion resistance. The introduction of zirconium into the coatings significantly increases hardness and bio-corrosion resistance, with charge transfer resistance improving from ~40 kΩ.cm2 to ~990 kΩ.cm2 after immersion. The findings highlight the synergistic effects of copper and zirconium in optimizing the performance of protective coatings for biomedical applications.

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