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Can I read The mechanism of nucleophilic substitution at silicon. Action of organometallic reagents on chiral bifunctional silanes on EtoBox?
The mechanism of nucleophilic substitution at silicon. Action of organometallic reagents on chiral bifunctional silanes by R.J.P. Corriu; G.F. Lanneau is a Chemistry article available to read on EtoBox.
What is The mechanism of nucleophilic substitution at silicon. Action of organometallic reagents on chiral bifunctional silanes about?
The study of nucleophilic substitution of monofunctional organosilanes has been extended to bifunctional derivatives. The reactions are both selective and stereoselective. Our results can be interpreted in terms of leaving group polarisability and the softness/hardness of the attacking nucleophile. The presence of two electronegative substituents only slightly modifies the stereochemistry. A pseudorotation mechanism could not explain the retention observed in certain cases. We envisage two possible modes of attack, either with axial or equatorial entry, leading respectively to inversion or retention at the silicon atom.
Who reads The mechanism of nucleophilic substitution at silicon. Action of organometallic reagents on chiral bifunctional silanes?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- R.J.P. Corriu; G.F. Lanneau
- Publisher
- Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)
- Published
- 1974
- Language
- EN
- Field
- Chemistry (Physical Sciences)