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Potentiometric Flow-injection Analysis of Alkali and Alkaline Metals with a Tungsten Oxide Coated Nafion Film Sensor by ZuLiang Chen; P. W. Alexander is a Engineering article available to read on EtoBox.

What is Potentiometric Flow-injection Analysis of Alkali and Alkaline Metals with a Tungsten Oxide Coated Nafion Film Sensor about?

## Potentiometricflow-injectionanalysisofalkaliand alkaline metals was possible using a novel type of electrochemical sensor based on tungsten oxide wire coated Nafion electrode. The response characteristics of a tungsten oxide coated Nafion sensor for alkali and alkaline metals were investigated by potentiometric flow-injection measurement. It was found that ion exchange preconcentrated metals by electrostatic interaction and also excluded the anion interference in the presence of Nafion film on the surface of the electrode. This sensor gave a linear response in the range of 4 ‫ן‬ 10 ‫5מ‬ -1 ‫ן‬ 10 ‫2מ‬ M with detection limits of 10 ‫6מ‬ M. The slopes of 39.2 and 44.4 mV/ decade for the K ‫ם‬ and Ca ‫ם2‬ were obtained. Compared to bare electrode, the coated Nafion sensor offered a fast response time (Ͻ10 s), a stable baseline, and no anion interference.

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Author
ZuLiang Chen; P. W. Alexander
Publisher
John Wiley and Sons; Wiley (John Wiley & Sons); VCH Publishers; Wiley (ISSN 0895-7533)
Published
1997
Language
EN
Field
Engineering (Physical Sciences)

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