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This document presents a theory of copolymer crystallization. The theory shows that copolymer crystals do not achieve an equilibrium composition during crystallization. Rather, the fraction of the minor component (component B) is kinetically controlled and determined by growth rates. Specifically, the faster the crystal growth relative to equilibration processes, the greater the excess inclusion of the minor component B beyond its equilibrium concentration. The document applies the kinetic theory of Lauritz

Author

Gersón Jácome

Language

EN