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Structurally Biased 2-Fluoroallyl Cations as Generated - or not Generated - in Cyclopropane Ring-opening Reactions by Manfred Schlosser; Yvonne Bessière is a Chemistry article available to read on EtoBox.
What is Structurally Biased 2-Fluoroallyl Cations as Generated - or not Generated - in Cyclopropane Ring-opening Reactions about?
## Abstract The silver ion‐catalysed ring‐opening of 2‐__t__‐butyl‐1‐chloro‐1‐fluoro‐2‐methyl‐cyclopropane (see __Scheme 2__) gave the expected mixture of primary and tertiary fluoroalkenols, whereas a tricyclic analog (bornane‐__spiro__‐chlorofluorocyclopropane) (see __Scheme 3__) exclusively underwent a __Wagner__/__Meerwein__ rearrangement upon ionization to lose finally a proton affording a 2‐fluoro‐1,4‐diene.
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- Author
- Manfred Schlosser; Yvonne Bessière
- Publisher
- John Wiley and Sons; Wiley (John Wiley & Sons); Wiley-Blackwell; Wiley (ISSN 0018-019X)
- Published
- 1977
- Language
- EN
- Field
- Chemistry (Physical Sciences)