Can I read Product Distributions in the Addition of the Hydride Ion to Cyclopentadienyliron Complexes of Substituted Benzenes on EtoBox?

Product Distributions in the Addition of the Hydride Ion to Cyclopentadienyliron Complexes of Substituted Benzenes by R.G. Sutherland; C.H. Zhang; R.L. Chowdhury; A. Piórko; C.C. Lee is a Chemistry article available to read on EtoBox.

What is Product Distributions in the Addition of the Hydride Ion to Cyclopentadienyliron Complexes of Substituted Benzenes about?

Fifteen [C,H,(X)FeCp]+ cations with substituents X having different electrondonating or electron-withdrawing effects were treated with NaBH, in glyme or THF. The relative distributions of products from o-, m-, pand ipso-additions of the hydride ion to the arene ring were determined by high resolution 'H NMR. For the $-N, N-dimethylaniline-$-cyclopentadienyliron cation with the most electrondonating of the substituents studied, only m-and p-hydride addition products were obtained, while in the reaction with the q6-nitrobenzene-q5-cyclopentadienyliron cation, which contained the most electron-withdrawing of the substituents investigated, only the o-addition product was formed. For the other 13 cations, with X = C,

Who reads Product Distributions in the Addition of the Hydride Ion to Cyclopentadienyliron Complexes of Substituted Benzenes?

Author

R.G. Sutherland; C.H. Zhang; R.L. Chowdhury; A. Piórko; C.C. Lee

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1987

Language

EN

Field

Chemistry (Physical Sciences)