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Tetrathiafulvalene as a Trigger for Sequential Radical Translocation and Functionalisation by Michael J. Begley; John A. Murphy; Stephen J. Roome is a Chemistry article available to read on EtoBox.

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Aryl diazonium salts react with tetrathiafulvalene to generate aryl radicals which undergo ineamolecular hydrogen atom abstractions; the radicals which result lead to (a) oxidized product or (b) undergo an unprecedented carbon-carbon bond formation with the radicakation of tetrathiafulvalene. We have recently witnessed remarkable reactions using tetrathiafulvalene (TTF) as an electron donor. Diazonium salts were converted to aryl radicats which underwent cyclisation. The product alkyd radicals were then transformed into alcohols, ethers or amidesl.

Who reads Tetrathiafulvalene as a Trigger for Sequential Radical Translocation and Functionalisation?

Author

Michael J. Begley; John A. Murphy; Stephen J. Roome

Publisher

Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)

Published

1994

Language

EN

Field

Chemistry (Physical Sciences)