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## Selectivities of oxometalloporphyrin complexes towards hydrogen atom abstraction from substrtuted toluenes decrease m the order Cr =0 2 Fe= 0 z Mn-0, which IS m accord with the force constants of the M=O bonds in these model oxygenases. (Cl)(TPP)M"=O + RH -(Cl)(TPP)M-O@-H--R6+ -[(C1)(TPP)MW-OH,R] -(CI)(TPP)M"' I ROH [(Cl)(TPP)MW-OH,R] -(Cl)(TPP)M'"-OH t R 2 RCI + ROH
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It is typically read by researchers, students, and practitioners in Chemistry.
- Publisher
- Elsevier Science; Elsevier ; Elsevier Ltd.; Elsevier BV (ISSN 0040-4039)
- Published
- 1991
- Language
- EN
- Field
- Chemistry (Physical Sciences)