Can I read Isonitrile substitution reactions of Co4(μ4-SiR)2(CO)11 clusters and the structure of Co4(μ4-SiC6H4OMe)2(CO)7(XyNC)4 on EtoBox?

Isonitrile substitution reactions of Co4(μ4-SiR)2(CO)11 clusters and the structure of Co4(μ4-SiC6H4OMe)2(CO)7(XyNC)4 by Cameron Evans; Brian K. Nicholson is a Chemistry article available to read on EtoBox.

What is Isonitrile substitution reactions of Co4(μ4-SiR)2(CO)11 clusters and the structure of Co4(μ4-SiC6H4OMe)2(CO)7(XyNC)4 about?

The substitution of carbonyl ligands by isonitriles on Co 4 (m 4 -SiC 6 H 4 R) 2 (CO) 11 (R0/H, OMe, NMe 2 ) clusters has been examined. The reactions could be monitored by electrospray ionisation mass spectrometry, identifying the substituted products as either protonated [M'/H] ' (R 0/NMe 2 ) or oxidised [M] ' (R0/H, OMe) ions. Evidence for substitution of up to nine carbonyl ligands was found and the structure of tetra-substituted example, Co 4 (m 4 -SiC 6 H 4 OMe) 2 (CO) 7 (XyNC) 4 , was determined.

Who reads Isonitrile substitution reactions of Co4(μ4-SiR)2(CO)11 clusters and the structure of Co4(μ4-SiC6H4OMe)2(CO)7(XyNC)4?

Author

Cameron Evans; Brian K. Nicholson

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

2003

Language

EN

Field

Chemistry (Physical Sciences)