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Can I read Alkyl 1,1-dialkoxy-alkane- and -arene-carboxylates. Part IV 1-alkoxyalkyl carboxylates on EtoBox?
Alkyl 1,1-dialkoxy-alkane- and -arene-carboxylates. Part IV 1-alkoxyalkyl carboxylates by J. W. Scheeren; R. J. F. Nivard is a Chemistry article available to read on EtoBox.
What is Alkyl 1,1-dialkoxy-alkane- and -arene-carboxylates. Part IV 1-alkoxyalkyl carboxylates about?
## Abstract Aldehydes can be converted into 1‐alkoxyalkyl carboxylates under mild conditions by reaction with dialkoxymethyl carboxylates in the presence of carboxylic acids. A mechanism has been proposed to explain the appearance of orthoformate during the reaction, and the accelerating effect of this compound on the formation of 1‐alkoxyalkyl carboxylates. Thermostable 1‐alkoxyalkyl carboxylates can be prepared also from acetals and carboxylic acids though in low yields. Higher homologues were obtained from the 1‐alkoxyalkyl acetates by exchange of the acid group in a distillation procedure. In a similar way formates were obtained from butyrates and the formic acid/triethylammonium formate azeotrope.
Who reads Alkyl 1,1-dialkoxy-alkane- and -arene-carboxylates. Part IV 1-alkoxyalkyl carboxylates?
It is typically read by researchers, students, and practitioners in Chemistry.
- Author
- J. W. Scheeren; R. J. F. Nivard
- Publisher
- Elsevier Science; Wiley (John Wiley & Sons); Royal Netherlands Chemical Society; Wiley (ISSN 0165-0513)
- Published
- 2010
- Language
- EN
- Field
- Chemistry (Physical Sciences)