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Supramolecular assembling of tectonic [TlI(RC6H4NNNC6H4R)]2 [R=p-NO2] through metal–η2-arene π-interactions and metal⋯O secondary bonding: Synthesis and X-ray characterization of a bis diaryl symmetric-substituted triazenide complex of thallium(I) by Manfredo Hörner; Gelson Manzoni de Oliveira; Leandro Bresolin; Adriano Bof de Oliveira is a Chemistry article available to read on EtoBox.

What is Supramolecular assembling of tectonic [TlI(RC6H4NNNC6H4R)]2 [R=p-NO2] through metal–η2-arene π-interactions and metal⋯O secondary bonding: Synthesis and X-ray characterization of a bis diaryl symmetric-substituted triazenide complex of thallium(I) about?

Deprotonated 1,3-bis(4-nitrophenyl)triazene reacts with an aqueous solution of TlNO 3 to give dark-red crystals of {[Tl I (RC 6 H 4 NNNC 6 H 4 R)] 2 } n [R = p-NO 2 ], a symmetric-substituted triazenide complex ''polymer'' of Tl I . The centrosymmetric tectons [Tl I (RC 6 H 4 NNNC 6 H 4 R)] 2 are related by translation and attain unidimensional chains along the c-axis through TlÁ Á ÁO bonding. The supramolecular bidimensional (2D) assembling of the dimeric tectons is achieved through weak secondary p-interactions of the type Tl-g 2 -arene between the unidimensional chains.

Who reads Supramolecular assembling of tectonic [TlI(RC6H4NNNC6H4R)]2 [R=p-NO2] through metal–η2-arene π-interactions and metal⋯O secondary bonding: Synthesis and X-ray characterization of a bis diaryl symmetric-substituted triazenide complex of thallium(I)?

Author

Manfredo Hörner; Gelson Manzoni de Oliveira; Leandro Bresolin; Adriano Bof de Oliveira

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

2006

Language

EN

Field

Chemistry (Physical Sciences)