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1,47-Triazacycloalkane complexes of palladium(II) with a many membered chelate ring bridging trans-positions by Matsuo Nonoyama; Kiyoko Nonoyama is a Chemistry article available to read on EtoBox.

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Palladium(II) complexes of 1,4,7-tnkzacycloalkanes (L), ~~~H(cH,)~~~H(cH,)~H(~H~)~ (r = 2,5, 6, 7, 8, and IO), were prepared and characterized. In the complexes [PdCl,(LH)] C104\*H,0 obtained for the ligands with a small ring size (r = 2 and 5) the cyclic triamines were bidentate and one amino group protonated, while in the complexes [PdClL] C104 of the ligands with a large ring size (r = 6, 7, 8, and IO) the triamines were terdentate and the longest polymethylene chains, (CHJ,, bridge the tram positions of a square plane.

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Author

Matsuo Nonoyama; Kiyoko Nonoyama

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0020-1693)

Published

1979

Language

EN

Field

Chemistry (Physical Sciences)