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This document reports on a study of the interaction between diphenyl phosphoric acid (DPP) and quinaldine (Qu) in dichloromethane. In contrast to expectations for a simple acid-base titration, NMR spectroscopy revealed the formation of multimers consisting of at least one base and two acid molecules, in addition to proton transfer and ion pair formation. Even with excess base, about one third of intermolecular aggregates were multimers. Quantitative analysis showed the acid-base association constant was onl

Author

Julian Puerta de Jesus

Language

EN