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O-confusion Approach in Construction of Carbaporphyrinoids by Miłosz Pawlicki; Lechosław Latos-Grażyński is a Chemistry article available to read on EtoBox.

What is O-confusion Approach in Construction of Carbaporphyrinoids about?

Carbaporphyrinoids provide a suitable macrocyclic platform for organometallic investigations providing unique capabilities for reversible modifications of a macrocyclic structure. Alteration of a coordination core is the route of choice for stabilizing unusual metal ion oxidation states and coordination geometries. This concise review presents the general characteristic of carbaporphyrinoid focusing, however, on oxaporphyrin derivatives. Incorporation of a furan ring into a porphyrin frame results in the formation of 21-oxaporphyrin or its O-confused counterpart. This particular couple, constructed applying the O-confusion concept, was selected to illustrate the developments in the field of carbaporphyrinoids. The coordination chemistry in the O-confused porphyrin surrounding takes advantage of the unique set of four meridional donor atoms (CNNN) constrained in the regular porphyrin-like framework. The subtle interplay between their structural flexibility, perimeter substitution, coordination, and aromaticity was detected for oxacarbaporphyrinoids. The oxidation state of a central metal ion is a factor, which determines the ligand molecular structure. The adjacency of the metal and

Who reads O-confusion Approach in Construction of Carbaporphyrinoids?

Author

Miłosz Pawlicki; Lechosław Latos-Grażyński

Publisher

John Wiley and Sons; Wiley (John Wiley & Sons); John Wiley & Sons Inc.; Wiley (ISSN 1527-8999)

Published

2006

Language

EN

Field

Chemistry (Physical Sciences)