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Elaboration of acyl ligands: Preparation and reactivity of the anion [(η5-C5,H5)Fe(CO)(PPh3)(COCH2)]− by Nurgün Aktogu; Hugh Felkin; Gordon J. Baird; Stephen G. Davies; Oliver Watts is a Chemistry article available to read on EtoBox.

What is Elaboration of acyl ligands: Preparation and reactivity of the anion [(η5-C5,H5)Fe(CO)(PPh3)(COCH2)]− about?

Addition of electrophiles to the anion [($-C,H,)Fe(CO)(PPh3)(COCH,)]-Li+ allows the acyl ligand in the complex ($-C,H,)Fe(CO)(PPh3)(COCH,) to be developed. The unstable P-oxo-acyl complexes ( T$-C,H,)Fe(CO)(PPh,)-(COCHJOR) (R = H, Me, Ph, OEt) undergo facile carbon-carbon bond cleavage to generate the carbanions (RCOCH,) and the cation [( $-C,H,)Fe(

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Author

Nurgün Aktogu; Hugh Felkin; Gordon J. Baird; Stephen G. Davies; Oliver Watts

Publisher

Elsevier Science; Elsevier ; Elsevier BV (ISSN 0022-328X)

Published

1984

Language

EN

Field

Chemistry (Physical Sciences)